Agilent IonSpec OFT-9 Application Note 00618 Characterization of Self-Assembling Metallosupramolecular Complexes by Elec

About this manual

The document details a study on self-assembling metallosupramolecular complexes, specifically focusing on square and triangular geometries formed by bipyridine ligands and platinum-diphenylphosphinopropane complexes. The research highlights the advantages of using high-resolution electrospray ionization Fourier Transform mass spectrometry (ESI-FTMS) to analyze these fragile assemblies under dilute conditions.

What's inside

• Introduction
• Methods
• Discussion
• Isolation and IRMPD
• Conclusion

Frequently asked questions

Which instrument was used for the mass spectral studies?

The study utilized an IonSpec OFT hybrid FTMS instrument equipped with a 9.4T superconducting magnet and electrospray ionization source.

What was the typical flow rate applied for ESI analysis?

A typical flow rate of 0.5 pL/min was applied.

How is the fragmentation of selected species controlled?

Fragmentation is controlled by varying the length of irradiation time or changing the power of the irradiation beam.