This document is an application note about the use of the Varian 210-MS ion trap mass spectrometer and V:Results™ GC/MS software for gas chromatography mass spectrometry analysis. The method is applicable for the determination of volatile organic compounds in various solid waste samples, including different water content samples such as air sampling trapping media, ground and surface water, aqueous sludges, caustic liquors, waste solvents, oily wastes, mousses, tars, fibrous wastes, polymeric emulsions, filter cakes, spent carbons, spent catalysts, soils, and sediments.