Agilent Improving the Analysis of Organotin Compounds Using Retention Time Locked Methods and Databases

This application note describes a retention time locked (RTL) gas chromatography-mass spectrometry (GC/MS) method for the analysis of derivatized organotin compounds. Three retention time locked libraries are made available, corresponding to three different derivatization methods. The retention time databases allow easy peak location and identification of the target solutes based on mass spectra and retention times.


Agilent Improving the Analysis of Organotin Compounds Using Retention Time Locked Methods and Databases - cover page
Brand
Agilent
Category
Other Electronics
Document type
Application Note
Language
English
Pages
10
File format
PDF
File size
134 KB
Published
12 June, 2012
Updated
01 October, 2023
MD5 checksum
AD5C87EA607F39FC5E7D71FCF76D82A8

About this manual

This document details a method for analyzing organotin compounds using gas chromatography/mass spectrometry (GC/MS). It addresses the complexity of interpreting mass spectra for these compounds by utilizing retention time locked (RTL) libraries. The method allows for reliable peak allocation and identification based on both mass spectra and fixed retention times, even after column maintenance or changes.

What's inside

  • Introduction
  • Derivatization Methods
  • Experimental
  • Organotin Compounds and Characteristic Ions
  • Retention Time Locked Libraries

Frequently asked questions

What is the purpose of the retention time locked method described in this document?

The method allows for easy peak location and identification of target solutes based on mass spectra and retention times.

What are the three types of organotin derivatives considered for analysis?

The document considers methyl-derivatives, pentyl-derivatives, and ethyl-derivatives for the analysis of organotin compounds.

What are the specific ions monitored for Triethyltin (TET) in Derivatization 1?

The characteristic ions for Triethyltin (TET) in Derivatization 1 are 193, 191, 185, and 163.

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